By Andreas Karachalios (auth.)
This research, the 1st accomplished account of Erich Hückel's occupation, examines his clinical paintings in addition to his value for the emergence of quantum chemistry as an self sufficient self-discipline in Germany throughout the Nineteen Thirties. Hückel started his profession via learning quantum physics in Göttingen, yet his heritage in chemistry led him to take in pioneering learn at the physics of chemical bonding.
Drawing on numerous assets, Andreas Karachalios deals a probing account of fast-breaking advancements in quantum thought that cleared the path for Hückel's examine. In Göttingen and later in Leipzig, Hückel interacted with major figures not just in quantum physics and actual chemistry but additionally with others in within sight fields, together with natural chemistry and mathematics.
During his later profession in Marburg, Hückel clashed with Linus Pauling over the houses of the benzine molecule. with a view to savor this controversy, Karachalios provides a quick account of the mathematical formalism of spin invariants, with either Hückel and Pauling utilized in their analyses, notwithstanding with various interpretations. This serves not just to explain their modifications but additionally to demonstrate the significance of the quantum-mechanical thought of resonance for chemistry at this time.
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Additional resources for Erich HÜckel (1896–1980): From Physics to Quantum Chemistry
XVI Physics, pp. 125–147. 75 At the beginning of the summer term in 1921 the position had just become vacant because the recent auxiliary assistant Kratzer had received an appointment as full professor of theoretical physics at the University of Münster. So Hückel accepted Hilbert’s offer to succeed Kratzer for 1 year at the mathematics department of the University of Göttingen. It remained a puzzle to Hückel, however, why Hilbert had offered him the position. Hilbert was mainly interested in theoretical physics and Erich had taken his doctorate in experimental physics.
Cf. Ein Gelehrtenleben, p. 121.
As Helge Kragh has aptly described, Hückel obtained from Born his first demanding theoretical assignment along with his first dabblings with quantum theory in a new peripheral field situated between physics and chemistry. ”96 The quantum-theoretical considerations on polyatomic molecules by Born and Hückel certainly do mirror Born’s mentality and stylistic orientation as a scientist. : Ein Gelehrtenleben, p. 85. 92 Ibid. : Briefwechsel 1916–1955, p. 106. : Zur Quantentheorie mehratomiger Molekeln, in: PZ 24 (1923), 1–12.